Kovac said at his pre-match press conference ahead of Tuesday’s last-16 first leg: “I want to say once again we are playing tomorrow against an opponent where it is the most difficult draw.
“The atmosphere will definitely be good, but I’m sure my players have gone through a lot of big games with great atmospheres, so that’s not an argument that we shouldn’t be able to compete tomorrow.
“We just have to get into the game, be focused, stand up to the first attacks and then we’ll try to play our game, and (then) we can get a successful result.
“The Champions League is undoubtedly special and tomorrow when the lads leave the hotel or come into the stadium, they’ll know what it’s about, why they need venues like this and opponents like this.
“I’m completely convinced everybody will be right in the head and produce performances they have to to get a result tomorrow.”
Bayern are currently second themselves, behind Klopp’s old club Borussia Dortmund, in the Bundesliga, which they won last term for a sixth successive season. They exited last year’s Champions League in the semi-finals.
Former Bayern and Croatia player Kovac took charge at the club last summer, succeeding the retiring Jupp Heynckes.
The visitors look set to be without Jerome Boateng on Tuesday, the defender having been hit by gastroenteritis and not travelled with the squad.
Winger Franck Ribery is another player who did not come across from Germany with his team-mates on Monday, following the birth of his daughter during the night, but he was due to arrive ahead of the match.
It appears Kingsley Coman, who scored twice before coming off with an injury in Friday’s 3-2 win at Augsburg, will be available.
Leon Goretzka trained individually on Monday having picked up a slight ankle problem. Thomas Muller is suspended.