The Reds are seeking a swift response to their 2-0 loss at Napoli last time out, and head to west London to meet a new-look Blues side in mixed form so far.
They also suffered a penalty-shootout defeat to Liverpool in the UEFA Super Cup, though that clash in Istanbul is likely to be very different to today’s at Stamford Bridge.
Both managers have a point to prove after their European setbacks, and for Klopp, the challenge is to maintain a perfect start to the league campaign and stay top of the table.
Check This Is Anfield for the latest team news ahead of the match.
You can also follow the game by downloading the This is Anfield app, including lineups, live commentary and all the reaction and analysis.
The match gets underway at 4.30pm (BST)—or 11.30am in New York, 8.30am in Los Angeles, 1.30am (Monday) in Sydney, 7.30pm in Dubai and 6.30pm in Nairobi.
Check our Rest of the World TV guide below for a list of TV broadcasters showing the match live.
Rest of the World
Supporters can find the Reds’ clash at Stamford Bridge on the following channels worldwide:
beIN SPORTS CONNECT, beIN Sports HD 2, RMC Sport 1, SuperSport 3 Africa, SuperSport Maximo, ESPN2 Sur, ESPN Play Sur, Optus Sport, Sky Sport 1 HD, Sky Go, Idman TV, Belarus 5, VOOsport World 1, Play Sports 2, SportKlub 1 Serbia, Watch ESPN Brasil, ESPN Brasil, Astro Go, DAZN, PPTV Sport China, QQ Sports Live, Sky HD, Sportklub 1 Croatia, Premier Sport, DIGI GO, Viaplay Denmark, Xee, TVPlay SportsX, TVPlay Sports, Viasat Sports Premium, Viasat Football HD, Viaplay Finland, RMC Sport en direct, Canal+ France, Cosmote Sport 1 HD, Now Player, Now E, 621 Now Premier League 1, 620 Now Premier League TV, SiminnSport, Mola TV, Sky Sports Premier League Ireland, Sky Sport Football, NOW TV, SKY Go Italia, Sky Sport Uno, Setanta Sports Kazakhstan, MaxTV Go, GO TV Anywhere, TSN2 Malta, Blue To Go Video Everywhere, SPS HD, Spark Sport, TV2 Sumo, TV2 Sport Premium, Sport TV1, Sport TV LIVE, SportKlub 1 Slovenia, DAZN Spain, Viaplay Sweden, Eleven Sports Plus, Eleven Sports 1 Taiwan, True Premier Football HD 1, Truevisions Anywhere, True Premier Football HD 2, S Sport+, Setanta Sports Ukraine
You can follow all the action this afternoon and throughout 2019/20 with us by downloading the This is Anfield app for iPhone and Android for free.